Millicent (Millie) Firestone

Thrust Leader, Center for Integrated Nanotechnologies
Science Thrust: Soft, Biological and Composite Nanomaterials

Phone 505-665-8554
Fax 505-665-9030
firestone@lanl.gov

MPA-CINT, MS K771
Los Alamos National Laboratory
Los Alamos, NM 87545


 

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Education and Training

Undergraduate: Indiana University of Pennsylvania, B.S. Chemistry
Graduate:          Northwestern University, Ph.D. Chemistry
Post-graduate:   University of Illinois, Urbana-Champaign

Research

Dr. Firestone’s research emphasizes the design, synthesis and characterization of hierarchical, self-assembled, soft materials that can exploit the native capabilities of biological molecules to store and transduce energy. The core research carried out under this effort involves the synthesis of amphiphilic monomers and macromers which self-organize into a variety of structured mesophases.  The mesophases are then “captured” as durable, robust nanostructured polymers that can be used as functional scaffolding for electronic and photonic connections between biomolecules (proteins) and inorganic materials.

Selected Publications

  • Ringstrand, B. S.; Seifert, S.; Firestone, M. A. “Preparation of a solution-processable, nanostructured ionic polyacetylene” J Poly Sci: Part B Poly Physics (2013), 51(16), 1215-1227.
  • Lee, S.; Seifert, S.; Firestone, M. A. “Multi-length scale evaluation of the temperature-tunable mechanical properties of a lyotropic mesophase”, Polymer J. Nature (2013), 45(2), 179-187. Cover article
  • Lee, S.; Ringstrand, B. S.; Stone, D. A.; Firestone, M. A. “Electrochemical activity of Glucose Oxidase on a poly(ionic liquid)- Au nanoparticle composite”, ACS Appl. Mater. Inter. (2012), 4(5), 2311-2317
  • Grubjesic, S.; Lee, B.; Seifert, S.; Firestone, M. A. “Preparation of a self-supporting cell architecture mimic by water channel confined photocrosslinking within a lamellar structured hydrogel”, Invited for inclusion in a themed issue of biomimetic soft matter, Soft Matter (2011), 7, 9695-9705.
  • Becht. G. A.; Sofos, M; Seifert, S.; Firestone, M. A. “Formation of a liquid-crystalline interpenetrating poly-(ionic liquid) network hydrogel”, Macromolecules (2011), 44, 1421-1428.
  • Edelstein, A.;Fink, D.;Musch, M.;Valuckaite, V.;Zabornia, O.;Grubjesic, S.;Firestone, M. A.;Matthews, J. B.; Alverdy, J. C. “Protective effects of nonionic tri-block copolymers on bile acid-mediated epithelial barrier disruption”, SHOCK Journal, 2011, 36(5),451-457.
  • Becht, G. A.; Lee, S.; Seifert, S.; Firestone, M. A. “Solvent tunable optical properties of a polymerized vinyl and thienyl substituted ionic liquid”, J. Phys. Chem. B (2010), 114, 14703-14711.
  • Lee, S. Becht, G. A.; Lee, B.; Burns, C. T.; Firestone, M. A., “Electropolymerization of a bifunctional ionic liquid monomer yields an electroactive liquid-crystalline polymer “Adv. Func. Mater. (2010), 20(13), 2063-2070. Cover Article.
  • Green, O.; Grubjesic, S.; Lee, S.; Firestone, M. A. “The design of polymeric ionic liquids for the preparation of functional materials”, Polymer Reviews. (2009), 19(10), 339. Invited review article.
  • Lee, S.; Cummins, M. D.; Willing, G. A.; Firestone, M. A. “Conductivity of ionic liquid-derived polymers with internal gold nanoparticle conduits”. J. Mater. Chem.  (2009), 19(43), 8092-8101. Cover Article.
  • Grubjesic, S., Firestone, M.A. “Cytoskeleton-mimetic reinforcement of self-assembled N,N’-dialylimidazolium ionic liquid monomer by copolymerization. Macromolecules” (2009), 42, 5461-5470.

Patents:

  • Multi-layer micro/nanofluid devices with bionanovalves” (U.S. patent 20130000764) granted 1/03/2013
  • Biomimetic Materials for Protein Storage and Transport” (U.S. Patent 8,168,746 ) granted  5/01/2012
  • Synthetic Biological Membrane with self-organizing properties” (U. S. Patent 6,537,575) granted 3/25/2003